Investigation of the 'rouge clair' glass on the Royal Gold
Cup
The Royal Gold Cup is unique in many
ways, and is a particularly fine example of Medieval enamelling on
gold, including use of the transparent red enamel, sometimes known
as ‘rouge clair’ or ‘ruby glass’. This colour was so highly
regarded at the time that it was considered worthy of mention in
Medieval inventories.
The cup itself dates to 1370–1380 while the
stem seems to be a later Tudor addition. It is one of the rare
survivors of the Commonwealth period in British history (1649–1660)
when so many gold objects were melted down. It is also the product
of a very high standard of craftsmanship and a superb example of
basse-taille enamelling.
A scientific study of the transparent red
enamel was carried out to establish how it was coloured. Ruby glass
is coloured by metallic nano-particles (one millionth of a
millimetre) of copper, silver or gold. While the earliest ruby
glasses are found in the Roman period (the Lycurgus cup in the
British Museum is one of the most famous examples and is a gold
ruby glass), the knowledge of gold ruby glass appears to have been
lost and only rediscovered in the late seventeenth century by the
German alchemist Kunkel. The first copper ruby glasses were
produced during medieval times and used for red stained-glass, but
the knowledge of how to make this red glass was lost by the
eighteenth century.

Ruby glass is difficult to use as an
enamel. It has to be melted to apply it to metal,
which can change the size and distribution of the small
metallic particles, spoiling the colour of the glass. It can change
either to an opaque liverish colour or to black. The sixteenth
century goldsmith Benvenuto Cellini found it was impossible to
enamel red onto silver or copper, though it could be done on
gold.
The Royal Gold cup has large areas of brilliant red enamel.
Examination in a scanning electron microscope of tiny fragments of
this transparent red enamel from the cup and its stem confirmed
that both are copper ruby glass.